曹心德(Cao Xinde)

特聘教授

電子郵件：xdcao@sjtu.edu.cn
辦公室電話：021-54741065
辦公地點：意昂4体育官方綠色環境樓
團隊網站🕢：http://gsgr.sjtu.edu.cn/CN/Default.aspx

研究方向

1. 土壤地下水汙染修復技術及應用

2. 土壤地下水環境多介質界面傳輸

3. 土壤生物炭固碳及生態環境效應

4. 綠色友好型環境多功能修復材料

• 1998年畢業於中國科技大學化學系，獲博士學位
•  1998-2000 南京大學環境意昂4講師
•  2000-2003 美國University of Florida 土壤與水科學系 博士後
•  2003-2005 美國Stevens Institute of Technology 環境系統中心 博士後
•  2005-2009 美國University of Florida 土壤與水科學系 研究員
•  2009年至今 意昂4体育平台 教授、長聘教授、特聘教授

意昂4体育官方特聘教授、二級教授👩🏿‍🦳、博士生導師，意昂4体育平台黨委書記，土壤地下水汙染修復技術研究所所長💿。國務院特殊津貼專家，上海市“浦江人才”計劃獲得者🍇，中國高被引學者，全球高被引用科學家。國際SCI期刊Chemosphere副主編🏺、Environmental Science and Pollution Research、環境化學 等編委📞。國際微量元素生物地球化學學會提名委員會委員，十三五國家重點研發計劃“地土壤汙染成因與治理技術”重點專項編製專家🏣，國家環境基準專家委員會委員，中國土壤學會土壤環境專業委員會委員，長三角區域生態環境保護標準一體化專家咨詢委員會委員，上海市環境科學學會理事，上海市化學化工學會環境科學與工程專業委員會副主任🫸🏻，上海市汙染場地修復技術研究中心技術委員會主任。

長期致力於土壤地下水汙染修復技術👨‍👦、土壤地下水環境多介質界面傳輸、土壤生物炭固碳技術🈹、綠色友好型環境修復材料等方面的研究。主持國家自然科學基金重點項目/面上項目、國家重大專項/重點研發計劃課題🖥、科技部國際合作項目、國家環保行業科研專項課題🥉、上海市科委重大課題以及企業委托等項目。在土壤地下水重金屬介質多界面遷移轉化及生物地球化學過程研究方面取得了系列創新成果，在Nat. Commun., Sci. Bull., Environ. Sci. Technol., Water Res.等期刊上發表SCI論文210多篇👊🏼。建立了土壤重金屬化學穩定化、汙染土壤地下水一體化🎞、重金屬物理分級分離𓀜🧞‍♂️、植物固定與提取等修復技術🧛🏿‍♀️，並成功應用於射擊場、電子加工場地👌🏻、化工廠🤽🏻、電鍍廠等典型汙染場地土壤及地下水修復工程10多項。獲省部級獎4項，其中教育部自然科學一等獎1項🦵🏼🙍🏻。

主講課程

科研成果

代表性主持科研項目（10項）

1. 國家自然科學基金重點項目（No. 42330706）：土壤-地下水典型重金屬多界面轉化與遷移過程 （2024-2027）

2. 上海市科委“科技創新行動計劃”科技支撐碳達峰碳中和專項項目（No. 22DZ1209400 ）🤽🏻‍♀️：二氧化碳植物捕獲強化調控與土壤長效封存關鍵技術研究與示範（2022-2025）

3. 國家自然科學基金聯合重點項目（No. U1906225）🏂🏻：山東海岸帶-近海區域重金屬的遷移轉化及生態環境效應（2020-2023）

4. 國家自然科學基金面上項目（No. 21777095）：生物炭膠體顆粒物協同土壤Cr(VI)的遷移轉化機製與數值模擬（2018-2021）

5. 國家自然科學基金重點項目（No. 21587002）：生物炭與土壤界面的電化學過程及其環境行為（2016-2020）

6. 國家重點研發計劃課題（No. 2018YFC1900704）🅾️🧑🏻‍🎤：城市環衛數據采集傳輸與人工智能分類收運集成技術（2018-2022）

7. 國家重大水專項子課題（No. 2017ZX07204002）👨🏽‍🎨：清淤底泥的資源化處置與新材料製備（2017-2020）

8. 國家自然科學基金面上項目（No. 21377081）：模擬人體消化道內汙染土壤重金屬鉛的形態轉化與生物可利用性（2014-2017）

9. 國家自然科學基金面上項目（No. 21077072）：一種雙功能吸附劑生物炭同時修復重金屬與有機物復合汙染土壤的分子機理（2011-2013）

10. 國家自然科學基金面上項目（No. 20877056）🥹：磷酸鹽誘導的鈍化修復重金屬復合汙染土壤的作用機製及評估體系（2009-2011）

代表性論文（50篇）

1. Xiaoyun Xu, Quan Qian, Yao Shi, Wenfeng Huang, Chengpeng Yuan, Lena Q. Ma, Willie G. Harris, Jiayin Dai*, Deyi Hou, Xinde Cao*. 2025 Cola beverage reduces risk of lead poisoning from accidental ingestion of contaminated soil particles in rat and swine models. Nature Communications. 16, 755

2. Kexin Chen, Xiaoyun Xu, Xing Li, Xiangyang Gui, Ling Zhao, Hao Qiu, Xinde Cao*. 2024 The colloidal stability of molybdenum disulfide nanosheets in different natural surface waters: Combined effects of water chemistry and light irradiation. Water Research 261, 121973

3. Jun Liang, Xiaoguang Duan, Xiaoyun Xu*, Zehong Zhang, Jingyi Zhang, Ling Zhao, Hao Qiu, Xinde Cao*. 2024 Critical functions of soil components for in situ persulfate oxidation of sulfamethoxazole: Inherent Fe(II) minerals-coordinated nonradical pathway. Environmental Science and Technology. 58, 1, 915-924.

4. Zehong Zhang, Jia Ren, Jun Liang, Xiaoyun Xu*, Ling Zhao, Hao Qiu, Hi Li, Xinde Cao. 2023 New insight into the natural detoxification of Cr(VI) in Fe-rich surface soil: crucial role of photogenerated silicate-bound Fe(II). Environmental Science and Technology. 57, 21370-21381.

5. Hao Qiu, Ziyang Lou, Xueyuan Gu, Yuanyuan Sun, Jun Wang, Wei Zhang, Xinde Cao*. 2022 Smart 6S roadmap for deciphering the migration and risk of heavy metals in soil and groundwater systems at brownfield sites nationwide in China. Science Bulletin 67, 1295-1299.

6. Yaqiang Wei, Chengpeng Yuan, Xiaoyun Xu*, Xiang Chen, Zhefan Ren, Xiangyang Gui, Ling Zhao, Hao Qiu, Xinde Cao*. 2022 Colloid formation and facilitated chromium transport in the coastal area soil induced by freshwater and seawater alternating fluctuations. Water Research 218, 118456.

7. Zibo Xu, Yulu Yu, Xiaoyun Xu*, Daniel CW Tsang, Chengbao Yao, Jing Fan, Ling Zhao, Hao Qiu, Xinde Cao. 2022 Direct and Indirect Electron Transfer Routes of Chromium(VI) Reduction with Different Crystalline Ferric Oxyhydroxides in the Presence of Pyrogenic Carbon. Environmental Science and Technology 56, 1724-1735.

8. Jun Liang, Xiaoguang Duan, Xiaoyun Xu*, Kexin Chen, Ying Zhang, Ling Zhao, Hao Qiu, Shaobin Wang, Xinde Cao. 2021 Persulfate Oxidation of Sulfamethoxazole by Magnetic Iron-Char Composites via Nonradical Pathways: Fe(IV) Versus Surface-Mediated Electron Transfer. Environmental Science and Technology 55, 10077-10086.

9. Jun Liang, Xiaoguang Duan, Xiaoyun Xu*, Kexin Chen, Fan Wu, Hao Qiu, Chengshuai Liu, Shaobin Wang, Xinde Cao. 2021 Biomass-derived pyrolytic carbons accelerated Fe(III)/Fe(II) redox cycle for persulfate activation: Pyrolysis temperature-depended performance and mechanisms. Applied Catalysis B-Environmental 297.

10. Yaqiang Wei, Xiaoyun Xu*, Ling Zhao, Xiang Chen, Hao Qiu, Bin Gao, Xinde Cao. 2021 Migration and transformation of chromium in unsaturated soil during groundwater table fluctuations induced by rainfall. Journal of Hazardous Materials 416.

11. Lei Pei, Fan Yang, Xiaoyun Xu*, Hongyan Nan, Xiangyang Gui, Ling Zhao, Xinde Cao. 2021 Further reuse of phosphorus-laden biochar for lead sorption from aqueous solution: Isotherm, kinetics, and mechanism. Science of the Total Environment 792.

12. Yaqiang Wei, Xinde Cao*. 2021 A COMSOL-PHREEQC Coupled Python Framework for Reactive Transport Modeling in Soil and Groundwater. Groundwater, 60, 284-294.

13. Zhefan Ren, Xiangyang Gui, Yaqiang Wei, Xiang Chen, Xiaoyun Xu, Ling Zhao, Hao Qiu, Xinde Cao*. 2021 Chemical and photo-initiated aging enhances transport risk of microplastics in saturated soils: Key factors, mechanisms, and modeling. Water Research 202, 117407.

14. Xing Li, Erkai He, Bing Xia, C.A.M. van Gestel, W.J.G.M. Peijnenburge, Xinde Cao, Hao Qiu*. 2020 Impact of CeO2 nanoparticles on the aggregation kinetics and stability of polystyrene nanoplastics: Importance of surface functionalization and solution chemistry. Water Research 186, 116324.

15. Jie Ji, Erkai He, Hao Qiu* W.J.G.M. Peijnenburge, C.A.M. van Gestel, Xinde Cao. 2020 Effective Modeling Framework for Quantifying the Potential Impacts of Coexisting Anions on the Toxicity of Arsenate, Selenite, and Vanadate. Environmental Science and Technology 54, 2379-2388.

16. Ling Zhao*, Dongling Xiao, Yang Liu, Huacheng Xu, Hongyan Nan, Xinde Cao*. 2019 Biochar as simultaneous shelter, adsorbent, pH buffer, and nutrient to promote biodegradation of high concentrations of phenol in wastewater. Water Research 172, 115494.

17. Xiaoyun Xu, Yuling Zheng, Bin Gao*, Xinde Cao*. 2019 N-doped biochar synthesized by a facile ball-milling method for enhanced sorption of CO2 and reactive red. Chemical Engineering Journal 368, 564-572.

18. Jun Liang, Xiaoyun Xu, Waqas Qamar Zaman, Xiaofang Hu, Ling Zhao, Hao Qiu, Xinde Cao*. 2019 Different mechanisms between biochar and activated carbon for the persulfate catalytic degradation of sulfamethoxazole: Roles of radicals in solution or solid phase. Chemical Engineering Journal 375, 121908.

19. Zibo Xu, Xiaoyun Xu, Xinyi Tao, Chengbo Yao, Daniel C W Tsang. Xinde Cao*. 2019 Interaction with low molecular weight organic acids affects the electron shuttling of biochar for Cr(VI) reduction. Journal of Hazardous Materials 378, 120705.

20. Ling Zhao, Yinghao Zhao, Hongyan Nan, Fan Yang, Hao Qiu, Xiaoyun Xu, Xinde Cao*. 2019 Suppressed formation of polycyclic aromatic hydrocarbons (PAHs) during Fe-preloaded barley straw pyrolysis. Journal of Hazardous Materials 121033

21. Yue Zhang, Xiaoyun Xu, Pengyu Zhang, Ling Zhao, Hao Qiu, Xinde Cao*. 2019 Pyrolysis-temperature depended quinone and carbonyl groups as the electron accepting sites in barley grass derived biochar. Chemosphere 232, 273~280.

22. Ming Chen, Xinyi Tao, Dengjun Wang, Zibo Xu, Xiaoyun Xu, Xiaofang Hu, Nan Xu, Xinde Cao* 2019 Facilitated transport of cadmium by biochar-Fe3O4 nanocomposites in water-saturated natural soils. Science of the Total Environment 684, 265~275.

23. Fan Yang, Zibo Xu, Yulu Yu, Bin Gao, Xiaoyun Xu, Ling Zhao, Xinde Cao* 2018 Kaolinite enhances the stability of the dissolvable and undissolvable fractions of biochar via different mechanisms. Environmental Science and Technology 52, 8321-8329.

24. Huang Huang, Ying Jiang, Xiaoyun Xu, Xinde Cao* 2018 In vitro bioaccessibility and health risk assessment of heavy metals in atmospheric particulate matters from three different functional areas of Shanghai, China. Science of the Total Environment 610-611, 546-554.

25. Yihan Dai, Yuan Liang, Xiaoyun Xu, Ling Zhao, Xinde Cao* 2018 An integrated approach for simultaneous immobilization of lead in both contaminated soil and groundwater: Laboratory test and numerical modeling. Journal of Hazardous Materials 342, 107-113.

26. Zibo Xu, Xiaoyun Xu, Daniel CW Tsang, Xinde Cao* 2018 Contrasting impacts of pre- and post-application aging of biochar on the immobilization of Cd in contaminated soils. Environmental Pollution 242, 1362-1370.

27. Ming Chen, Nangual Alim, Yitao Zhang, Nan Xu, Xinde Cao* 2018 Contrasting effects of biochar nanoparticles on the retention and transport of phosphorus in acidic and alkaline soils. Environmental Pollution 239, 562-570.

28. Xiaoyun Xu, Huang Huang, Yue Zhang, Zibo Xu, Xinde Cao* 2019 Biochar as both electron donor and electron shuttle for the reduction transformation of Cr(VI) during its sorption. Environmental Pollution 244, 423-430.

29. Ming Chen, Dengjun Wang, Fan Yang, Xiaoyun Xu, Nan Xu, Xinde Cao* 2017 Transport and retention of biochar nanoparticles in a paddy soil under environmentally-relevant solution chemistry conditions. Environmental Pollution 230, 540-549.

30. Xiaoyun Xu, Yinghao Zhao, Jingke Sima, Ling Zhao, Ondrew Masek, Xinde Cao* 2017 Indispensable role of biochar-inherent mineral constituents in its environmental applications: A review. Bioresource Technology 241, 887-899.

31. Ling Zhao, Zhenliang Ding, Jingke Sima, Xiaoyun Xu, Xinde Cao* 2017 Development of phosphate rock integrated with iron amendment for simultaneous immobilization of Zn and Cr(VI) in an electroplating contaminated soil. Chemosphere 182, 15-21.

32. Fan Yang, Ling Zhao, Bin Gao, Xiaoyun Xu, and Xinde Cao* 2016 The interfacial behavior between biochar and soil minerals and its effect on biochar stability. Environmental Science and Technology 50, 2264–2271.

33. Xiaoyun Xu, Daxuan Huang, Ling Zhao, Yue Kan, Xinde Cao* 2016 Role of inherent inorganic constituents in SO2 sorption ability of biochar derived from three biomass wastes. Environmental Science and Technology 50, 12957–12965.

34. Ling Zhao, Xinde Cao*, Wei Zheng, John Scott, B. K. Sharma, and Xiang Chen 2016 Co-pyrolysis of biomass with phosphate fertilizers to improve biochar carbon retention, slow nutrient release, and stabilize heavy metals in soil. ACS Sustainable Chemistry and Engineering 4, 1630–1636.

35. Xiaoyun Xu, Yue Kan, Ling Zhao, Xinde Cao* 2016 Chemical transformation of CO2 during its capture by waste biomass derived biochars. Environmental Pollution 213, 533-540.

36. Xiaoyun Xu, A Schierz, Nan Xu, Xinde Cao* 2016 Comparison of the characteristics and mechanisms of Hg(II) sorption by biochar and activated carbon. Journal of Colloid and Interface Science 463, 55–60.

37. Jingke Sima, Xinde Cao*, Ling Zhao, Qishi Luo 2015 Toxicity characteristic leaching procedure over- or under-estimates leachability of lead in phosphate-amended contaminated soils. Chemosphere 138, 744–750.

38. Feiyue Li, Xinde Cao*, Ling Zhao, Jianfei Wang, Zhenliang Ding 2014 Effects of mineral additives on biochar formation: Carbon retention, stability, and properties. Environmental Science and Technology 48, 11211–11217.

39. Ling Zhao, Wei Zheng, Xinde Cao* 2014 Distribution and evolution of organic matter phases during biochar formation and their importance in carbon loss and pore structure. Chemical Engineering Journal 250, 240-247.

40. Ling Zhao, Xinde Cao*, Ondrej Masek 2013 Heterogeneity of biochar properties as a function of feedstock sources and production temperatures. Journal of Hazardous Materials 256-257, 1-9.

41 Xinde Cao*, Lena Q Ma, Yuan Liang, Bin Gao, Willie Harris. 2011 Simultaneous immobilization of lead and atrazine in contaminated soils using dairy-manure biochar. Environmental Science and Technology 45, 4884-4889.

42. Xinde Cao and Willie Harris* 2010 Properties of dairy manure-derived biochar pertinent to its potential use in remediation. Bioresource Technology 101, 5222-5228.

43. Xinde Cao*, Lena Q Ma, Bin Gao, Willie Harris 2009 Dairy manure-derived biochar effectively sorbs lead and atrazine. Environmental Science and Technology 43, 3285–3291.

44. Xinde Cao, Lena Q Ma* 2009 Immobilization of Cu, Zn, and Pb in contaminated soils using phosphate rock and phosphoric acid. Journal of Hazardous Materials 164, 555-564.

45. Xinde Cao, Willie Harris*. 2008 Carbonate and Magnesium Interactive Effect on Calcium Phosphate Precipitation. Environmental Science and Technology 42, 436-442.

46. Xinde Cao, Wille G Harris*, MS Josan, VD Nair. 2007 Inhibition of calcium phosphate precipitation under environmentally-relevant conditions. Science of the Total Environment 383, 205-215.

47. Xinde Cao, Lena Q Ma*, Dean R Rhue, Chip S Appel. 2004 Mechanisms of lead, copper, and zinc retention by phosphate rock. Environmental Pollution 131, 435-444.

48. Xinde Cao, Lena Q Ma*, Ming Chen, DW Hardison, Willie G Harris. 2003 Lead Transformation and Distribution in the Soils of Shooting Ranges in Florida, USA. Science of the Total Environment 307, 179-189.

49. Xinde Cao, Lena Q Ma*, Ming Chen, DW Hardison, Willie G Harris. 2003 Weathering of lead bullets and their environmental effects at outdoor shooting ranges. Journal of Environmental Quality 32, 526-534.

50. Xinde Cao, Lena Q Ma* Ming Chen, SP Singh, Willie G Harris. 2002 Impacts of phosphate amendments on lead biogeochemistry at a contaminated site. Environmental Science and Technology, 36, 5296-5304.

榮譽獎勵

• 2024年  國務院政府特殊津貼
  
• 2021年 意昂4体育官方“教書育人獎”個人一等獎
• 2018年 上海市教學成果二等獎（排名第一）
• 2016年 上海交通大學教學成果特等獎（排名第一）
• 2011年 上海市“浦江人才”計劃獲得者
• 2003年 教育部自然科學一等獎（排名第三）